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      Acrylic Primer#1602 LANG丙烯酸底漆
    • 產品名稱:Acrylic Primer#1602 LANG丙烯酸底漆
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      SAFETY DATA SHEET

      Issue Date

      26-Sept-2014

      Revision Date

      14-July-2015

      Version 3

       

       

       

       

       

       

      1.  IDENTIFICATION

       

      Product Identifier

       

       

       

       

      Product Name

      ACRYLIC PRIMER / JET SEAL

       

       

      Other means of identification

       

       

       

      SDS#

      041

       

       

       

      UN/ID No

      UN1247

       

       

       

      Product Code

      1602, 1607, 1608 / 4102, 4106, 4107, 4108

       

       

      Recommended use of the chemical and restrictions on use

       

       

      Recommended Use

      Acrylic Primer - Acrylic bonding agent / Jet Seal - Acrylic sealing agent

      Acrylic Primer#1602 LANG丙烯酸底漆 

       

       

       

      2. HAZARDS IDENTIFICATION

      Classification

       

       

       

       

       

       

       

       

       

       

       

      Flammable liquids

       

       

       

      Category 2

       

      Skin Corrosion / Irritation

       

       

      Category 2

       

      Skin Sensitization

       

       

       

      Category 1

       

      Specific Target Organ Toxicity - Single Exposure

       

      Category 3

       

      (Respiratory)

       

       

       

       

       

      Signal word

      Danger

       

       

       

      Hazard statements

      H225

      Highly flammable liquid and vapor.

       

      H315

      Causes skin irritation.

      Acrylic Primer#1602 LANG丙烯酸底漆 

      H317 May cause an allergic skin reaction.

       

      H335 May cause respiratory irritation.

      Acrylic Primer / Jet Seal 041 v. 3 Page 1 of 8

      Appearance Clear Physical state Liquid Odor Acrid

       

      Precautionary Statements – Prevention

       

      P210 Keep away from heat/sparks/open flames/ hot surfaces. No smoking.

       

      P233 Keep container tightly closed.

       

      P240 Ground/bond container and receiving equipment.

       

      P241 Use explosion-proof electrical/ventilating/lighting/equipment.

       

      P242 Use only non-sparking tools.

       

      P243 Take precautionary measures against static discharge.

       

      P261 Avoid breathing dust/fume/gas/mist/vapors/spray.

       

      P264 Wash hands thoroughly after handling.

       

      P271 Use only outdoors or in a well-ventilated area.

       

      P272 Contaminated work clothing should not be allowed out of the workplace.

       

      P280 Wear protective gloves/protective clothing/eye protection/face protection.

       

      Precautionary Statements – Response

       

      P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediay all contaminated clothing. Rinse skin with water/shower.

       

      P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312 Call a POISON CENTER or doctor/physician if you feel unwell.

       

      P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P362 Take off contaminated clothing and wash before use.

       

      P370+P378 In case of fire: Use CO2, for extinction.

       

      Precautionary Statements – Storage

       

      P403+P233 Store in a well-ventilated place. Keep container tightly closed.

      P403+P235 Store in a well-ventilated place. Keep cool.

       

      Precautionary Statements – Disposal

       

      P501 Dispose of contents/container in accordance with local regulation.

       

      Hazardous Component(s) Contains methyl methacrylate

      for labeling

       

      Hazards not otherwise classified (HNOC) Not applicable

       

      Other Information Harmful to aquatic life

      3. COMPOSITION / INFORMATION ON INGREDIENTS

       

      Chemical Name

      CAS No

      Weight - %

      Trade Secret

      Methyl Methacrylate

      80-62-6

      <100

      *

      *Specific chemical weight has been

      withheld as a trade secret.

       

       

       

       

      4. FIRST AID MEASURES

      First aid measures

       

      Acrylic Primer / Jet Seal 041  v. 3

      Page 2 of 8


       

       

      ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Use personal protective equipment as required. Ensure adequate ventilation. Remove any contaminated clothing and wash thoroughly before reuse.

      Inhalation

      Remove victim to fresh air and keep at rest in a position comfortable for breathing. Keep patient warm and at

       

      rest. Call a physician or poison control center immediay.

      Eye contact

      Immediay flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing

       

      for at least 15 minutes. Call a physician immediay.

      Ingestion

      Do NOT induce vomiting. Drink plenty of water or milk immediay. Never give anything by mouth to an

       

      unconscious person. Provide an estimate of the time at which the material was ingested and the amount of

       

      the substance that was swallowed. Call a physician or poison control center immediay.

      Skin Contact

      Wash off immediay with plenty of soap and water. Take off contaminated clothing. Wash contaminated

       

      clothing before reuse. If skin irritation or rash occurs, get medical advice/attention.

      Most important symptoms and effects, both acute and delayed

      Symptoms

      May cause skin and eye irritation to the mucous membranes and upper respiratory tract.

      Indication of any immediate medical attention and special treatment needed

      Note to physicians

      Treat symptoms conventionally, after thorough decontamination.

       

       

       

      5. FIRE-FIGHTING MEASURES

       

      Extinguishing Media

       

      Suitable: Chemical foam, carbon dioxide (CO2), dry chemical

       

      Unsuitable: Water spray

       

      Specific hazards arising from the chemical

       

      For bulk size >1L – High temperatures, inhibitor depletion, accidental impurities, or exposure to radiation or oxidizers may cause spontaneous polymerizing reaction generating heat/pressure. Closed containers may rupture or explode during a runaway polymerization. Use a water spray or fog to reduce or direct vapors. Extremely flammable. Vapors are heavier than air and may spread along the floors. Vapors may travel to source of ignition and flash back. Heat/impurities may cause pressure to build and/or rupture closed containers, spreading fire, increasing risk or burns/injuries.

       

      Hazardous Combustion Products: Carbon oxides

       

      Sensitivity to Mechanical Impact: No

       

      Sensitivity to Static Discharge: Yes

       

      Protective equipment and precautions for firefighters

       

      As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fight fire from a safe location.

      6. ACCIDENTAL RELEASE MEASURES

       

      Personal precautions, protective equipment and emergency procedures

       

      Personal precautions

       

       

       

      Environmental precautions Prevent product from entering drains. Spillages or uncontrolled discharges into watercourses must

       

      be alerted to the appropriate regulatory body.

       

      Methods and material for containment and clean-up

       

      Method for containment Absorb with earth, sand or other non-combustible material and transfer to containers for later

       

      disposal. DO NOT use combustible materials such as sawdust.

       

      Method for clean-up Use only non-sparking tools. Wash all affected areas with plenty of warm water and soap.

       

      Acrylic Primer / Jet Seal 041 v. 3 Page 3 of 8


       

      If anticipated that prolonged and repeated skin contact will occur during use of this product, wear gloves for routine industrial use. If necessary, refer to US OSHA 29CFR SS1910.138 or the appropriate standards of Canada or the EC member states. Wear suitable protective clothing.

       

      Depending on the use of this product, safety glasses or goggles may be worn. If necessary, refer to US OSHA 29CFR SS1910.133, Canadian standards or the European Standard EN 166. Ensure that an eyewash station, sink or washbasin is available in case of exposure to eyes.

       

      Keep in original container.

      Strong oxidizing agents, strong reducing agents, free-radical generators, inert gases, oxygen scavengers

      Material has strong solvent properties and can soften paint and rubber.

      8. EXPOSURE CONTROLS / PERSONAL PROTECTION

      Consideration should be given to the work procedures involved and the potential extent of exposure as they may determine whether a higher level of protection is required. The following information is given as general guidance.

       

      Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks, flame and other sources of ignition (i.e. pilot lights, electric motors and static electricity). Protect from direct sunlight. Keep container closed to prevent water absorption and contamination. Methacrylate stored in bulk must be kept in contact with air (oxygen). Keep at a temperature not exceeding 25°C.

      7. HANDLING AND STORAGE

       

      Precautions for safe handling

       

      Advice on safe handling Observe precautions found on the label. Keep containers closed when not in use. All equipment used when handling the product must be grounded. Use non-sparking hand tools and explosion-proof electrical equipment. Avoid contact with skin and eyes. Avoid breathing vapors or mists. Use only in well-ventilated areas. Vapors are heavier than air and may travel along the floor and in the bottom of containers. Take precautionary measures against static discharges. Wash thoroughly after handling. Use personal protection recommended in Section 8. Contaminated work clothing should not be allowed out of the workplace. Keep away from heat, sparks, open flames, and hot surfaces. NO SMOKING.

       

      Conditions for safe storage, including any incompatibilities

       

      Storage Conditions

      Packaging materials

      Incompatible materials

      Exposure guidelines

       

      Chemical Name

      ACGIH TLV

      OSHA PEL

      NIOSH IDLH

      Methyl Methacrylate

      S 100 ppm

      TWA:100 ppm

      IDLH: 1,000 ppm

      80-62-6

      TWA: 50 ppm

      TWA: 410 mg/m3

      TWA: 100 ppm

       

       

       

      TWA: 410 mg/m3

      Appropriate engineering controls

      Engineering controls Apply technical measures to comply with the occupational exposure limits. Eyewash stations

      Individual protection measures, such as personal protective equipment

      Eye / face protection

      Skin and body protection

      Acrylic Primer / Jet Seal 041 v. 3 Page 4 of 8


       

      Respiratory protection

      Wear suitable respiratory equipment if exposure to levels above the occupational exposure limit is

       

       

      likely. A suitable mask with filter type A may be appropriate. In the event of formation of particularly

       

       

      high levels of vapor, a self-contained breathing apparatus may be appropriate.

      General hygiene considerations

      Handle in accordance with good industrial hygiene and safety practice.

       

       

       

       

       

       

      9. PHYSICAL AND CHEMICAL PROPERTIES

       

       

       

       

      Information on basic physical and chemical properties

       

       

      Physical state

       

      Liquid

      Odor

      Acrid

      Appearance

       

      Liquid

      Odor threshold

      Not determined

      Color

       

      Clear

       

       

      Property

       

      Values

      Remarks / Method

       

      pH

       

      Not determined

       

       

      Melting point /

      freezing point

      Not determined

       

       

      Boiling point / boiling range

      101°C / 214° F

       

       

      Flash point

       

      11.5°C / 52.7°F

       

       

      Evaporation rate

      3.1

      Butyl acetate = 1

       

      Flammability (solid, gas)

      n/a (liquid)

       

       

      Flammability limits in air

       

       

       

      Upper flammability limit

      12.5%

       

       

      Lower flammability limit

      2.12%

       

       

      Vapor pressure

       

      28mm Hg

      @ 20°C

       

      Vapor density

       

      3.5

      @15.5°C (Air = 1)

       

      Specific gravity

       

      0.891

      Water = 1

       

      Water solubility

       

      1.6 wt%

       

       

      Solubility in other solvents

      Not determined

       

       

      Partition coefficient

      Not determined

       

       

      Autoignition temperature

      421°C / 790°F

       

       

      Decomposition temperature

      Not determined

       

       

      Kinematic viscosity

      Not determined

       

       

      Dynamic viscosity

      Not determined

       

       

      Explosive properties

      Not determined

       

       

      Oxidizing properties

      Not determined

       

       

      Other information

       

       

       

      Density

       

      0.891 g/mL

       

       

       

       

       

       

       

       

      10. STABILITY AND REACTIVITY

       

       

       

       

       

      Reactivity

      Not reactive under normal conditions

       

       

       

      Chemical stability Unstable / reactive upon depletion of inhibitor

       

      Possibility of hazardous reactions

       

      None under normal processing

       

      Hazardous polymerization Hazardous polymerization may occur. Monomer vapors are inhibited and may form polymers in vent or flame arresters, resulting in blockage of vents.

       

      Conditions to avoid

       

      Temperatures above 25°C (77°F), localized heat sources (e.g. drum or band heaters), oxidizing conditions, freezing conditions, direct sunlight, ultraviolet radiation, inert gas blanketing

       

      Incompatible materials

       

      Strong oxidizing agents, strong reducing agents, free-radical generators, inert gases, oxygen scavengers

       

      Material has strong solvent properties and can soften paint and rubber.

       

      Hazardous decomposition products Carbon oxides

       

      Acrylic Primer / Jet Seal 041 v. 3 Page 5 of 8


       

       

      May cause allergic skin reaction.

      Not classifiable as a human carcinogen

       

       

      11. TOXICOLOGICAL INFORMATION

       

       

       

       

       

       

      Information on likely routes of exposures

       

       

       

      Product information

       

       

       

       

       

      Inhalation

      Avoid breathing vapors or mists.

       

       

       

      Eye contact

      Causes severe eye irritation.

       

       

       

      Skin contact

      Causes skin irritation.

       

       

       

      Ingestion

      Not expected to be toxic following ingestion of amount recommended for use.

       

      Component information

       

       

       

       

       

       

       

       

       

       

       

      Chemical Name

       

      ORAL LD50

      DERMAL LD50

       

      INHALATION LC50

      Methyl Methacrylate

       

      7872 mg/kg (rat)

      >5 g/kg (rabbit)

       

      400 ppm (rat) 1 h

      80-62-6

       

       

       

       

      4632 ppm (rat) 4 h

       

       

       

       

       

      Information on physical, chemical and toxicological effects

       

       

       

      Symptoms

      May cause skin and eye irritation. May cause irritation to the mucous membranes and upper respiratory tract.

       

      Delayed and immediate effects as well as chronic effects from short and long-term exposure

       

      Sensitization

       

      Carcinogenicity

       

      Chemical Name

      ACGIH

      IARC

      NTP

      OSHA

      Methyl Methacrylate

      -

      Group 3

      -

      -

      80-62-6

       

       

       

       

       

       

       

       

       

      IARC (International Agency

      for Research on Cancer)

      Group 3 IARC components are “not classifiable as human carcinogens”

       

      STOT – single exposure May cause respiratory irritation. May cause drowsiness or dizziness.

       

      Numerical measures of toxicity  Product Not determined

       

      The following values are calculated based on chapter 3.1 of the GHS document.

       

      ATEmix (oral)

      7874

      mg/kg

      ATEmix (dermal)

      5005

      mg/kg

      ATEmix (inhalation-gas)

      400

      mg/kg

      12. ECOLOGICAL INFORMATION

       

      Ecotoxicity Harmful to aquatic life.

       

      Chemical Name

      Algae / aquatic plants

      Fish

      Toxicity to

      Crustacea

       

       

       

      microorganisms

       

      Methyl

      170: 96 h

      125.5-190.7: 96 h Pimephales

      -

      69: 48 h Daphnia magna

      Methacrylate

      Psuedokirchneriella

      promelas mg/L LC50 static;

       

      mg/L EC50

      80-62-6

      subcapitata mg/L EC50

      153.9-341.8: 96 h Lepomis macrochirus mg/L

       

       

       

       

      LC50 static;

       

       

       

       

      170-206: 96 h Lepomis macrochirus mg/L

       

       

       

       

      LC50 flow -through;

       

       

       

       

      243-275: 96 h Pimephales promelas mg/L

       

       

       

       

      LC50 flow-through;

       

       

       

       

      326.4-426.9 96 h Poecilia reticulata mg/L

       

       

       

       

      LC50 static;

       

       

       

       

      >79: 96 h Oncorhynchus mykiss mg/L LC50

       

       

       

       

      flow-through;

       

       

       

       

      >79: 96 h Oncorhynchus mykiss mg/L LC50

       

       

       

       

      static

       

       

      Acrylic Primer / Jet Seal 041  v. 3

       

       

      Page 6 of 8


       

       

       

      Persistence and degradability Not readily biodegradable

       

       

       

       

       

       

       

      Bioaccumulation

      Not determined

       

       

       

       

       

       

       

      Mobility

      Potential for mobility in soil is very high.

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

      Chemical Name

       

       

       

      Partition coefficient

       

       

       

       

       

       

      Methyl Methacrylate

       

       

       

      0.7

       

       

       

       

       

       

       

      80-62-6

       

       

       

       

       

       

       

       

       

       

       

       

       

      Other adverse effects

      COD = 88% (28 days), DOC removal > 95% (28 days)

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

      13. DISPOSAL CONSIDERATIONS

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

      Waste treatment methods

       

       

       

       

       

       

       

       

       

       

       

       

       

      Disposal of wastes

       

      Follow all local and national government regulations in disposing material or contaminated

       

       

       

       

       

       

      packaging.

       

       

       

       

       

       

       

       

       

       

       

      For U.S. - Dispose of in accordance with federal, state and local regulations. When discarded, it is

       

       

       

       

       

       

      considered a hazardous waste by the EPA under RCRA. The reportable quantity for methyl

       

       

       

       

       

       

      methacrylate is 1000 lb. (40 CFR Part 302). Add excess inhibitor before disposing.

       

       

      Contaminated Packaging

       

      Reuse of empty drums or containers is not recommended. Employees should be advised of the

       

       

       

       

       

       

      potential hazards due to residual material associated with empty containers. Dispose of all empty

       

       

       

       

       

       

      containers properly in accordance with federal, state and local regulations.

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

      Chemical Name

       

      RCRA

       

      RCRA – Basis for Listing

      RCRA – D Series Wastes

       

      RCRA – U Series Wastes

       

       

      Methyl Methacrylate

       

      U162

       

       

      Included in waste stream;

      -

       

       

       

      U162

       

       

      80-62-6

       

       

       

       

       

      F039

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

      Chemical Name

       

       

      California Hazardous Waste Status

       

       

       

       

       

      Methyl Methacrylate

       

       

       

      Toxic Ignitable

       

       

       

       

       

       

       

      80-62-6

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

      14. TRANSPORTATION INFORMATION

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

      DOT

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

      UN / ID No

       

       

       

       

       

      UN1247

       

       

       

       

       

       

       

       

      Proper shipping name

       

       

       

       

       

      Methyl Methacrylate monomer, stabilized

       

       

       

       

      Hazard Class

       

       

       

       

       

      3

       

       

       

       

       

       

       

       

      Packing Group

       

       

       

       

       

      II

       

       

       

       

       

       

       

       

      Reportable Quantity (RQ)

       

       

       

       

       

      1000 lb.

       

       

       

       

       

       

       

      IATA

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

      UN / ID No

       

       

       

       

       

      UN1247

       

       

       

       

       

       

       

       

      Proper shipping name

       

       

       

       

       

      Methyl Methacrylate monomer, stabilized

       

       

       

       

      Hazard Class

       

       

       

       

       

      3

       

       

       

       

       

       

       

       

      Packing Group

       

       

       

       

       

      II

       

       

       

       

       

       

       

      IMDG

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

      UN / ID No

       

       

       

       

       

      UN1247

       

       

       

       

       

       

       

       

      Proper shipping name

       

       

       

       

       

      Methyl Methacrylate monomer, stabilized

       

       

       

       

      Hazard Class

       

       

       

       

       

      3

       

       

       

       

       

       

       

       

      Packing Group

       

       

       

       

       

      II

       

       

       

       

       

      Acrylic Primer / Jet Seal 041 v. 3 Page 7 of 8

       

       

       

       

      15. REGULATORY INFORMATION

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

      International Inventories

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

      TSCA

      Listed

       

      United States Toxic Substances Control Act, Section 8(b) Inventory

       

       

       

      DSL

      Listed

       

      Canadian Domestic Substances List

       

       

       

       

       

       

       

      EINECS

      Listed

       

      European Inventory of Existing Chemical Substances

       

       

       

      EU Regulations

      EC No. 1272/2008 (CLP) Classification, Labeling, Packaging

       

       

       

       

       

       

       

       

      Medical Devices Directive 93/42/EEC - Class I Medical Devices

       

       

       

       

       

       

       

      US Federal Regulations

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

      Chemical Name

       

      CAS

       

       

       

      Weight %

       

      SARA 313 Threshold Values %

       

       

      Methyl Methacrylate

       

      80-62-6

       

       

       

      < 100

       

       

      1.0

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

      SARA 311 / 312 Hazard Categories

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

      Chemical Name

       

       

      CWA – Reportable

       

       

      CWA – Toxic

       

       

      CWA – Priority

       

      CWA – Hazardous

       

       

       

       

       

      Quantities

       

       

      Pollutants

       

       

      Pollutants

       

      Substances

       

      Methyl Methacrylate

       

       

      1,000 lb.

       

       

      -

       

       

      -

       

       

      X

       

      80-62-6

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

      Chemical Name

       

      Hazardous Substances

       

      CERCLA /

       

       

      Reportable Quantity (RQ)

       

       

       

       

       

      RQs

       

      SARA RQ

       

       

      Final

       

       

       

      Methyl Methacrylate

       

      1,000 lb.

       

      -

       

       

       

      1,000 lb. / 454 kg

       

       

       

      80-62-6

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

      US State Right-to-Know Regulations

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

      Chemical Name

       

       

       

      CAS

       

       

      New Jersey

       

      Massachusetts

       

      Pennsylvania

      Methyl Methacrylate

      80-62-6

       

       

       

       

      X

       

      X

       

       

      X

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

       

      16. OTHER INFORMATION

       

      NFPA

      Health Hazards

       

      Flammability

      Instability

       

       

      2

       

      3

      2

       

      HMIS

      Health Hazards

       

      Flammability

      Physical Hazards

       

       

      2

       

      3

      2

       

      Issue Date

      26-Sept-2014

       

       

       

       

      Revision Date

      14-July-2015

       

       

       

       

      Revision Note

      Section 2 – revise classification categories, revise some Hazard Statements and Precautionary Statements,,

       

      add hazardous component for labeling info

       

       

      Information to be updated in due course

      Hazard pictograms listed in this SDS to be added to product label

       

      Disclaimer

       

      The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release. It is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

       

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